Coordination polymers towards applications: chirality by design
نویسندگان
چکیده
منابع مشابه
Chirality detection of two enantiomorphic 3D lanthanide coordination polymers by vibrational circular dichroism spectra.
Two enantiomorphic 3D lanthanide coordination polymers of {[Dy5(L)4(H2O)10][Dy(H2O)7][Na(H2O)5]}·(ClO4)7·(H2O)15 (1a for R and 1b for S) with chiral helical chains were synthesized based on an achiral ligand N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid (H3L) and Dy(ClO4)3. Crystal analysis revealed that 1a and 1b were crystallized in chiral space groups P4132 and P4332, respectively...
متن کاملCoordination polymers and metal-organic frameworks: materials by design.
The field of coordination polymers and metal–organic frameworks (MOFs) has evolved over a period of approximately 25 years to a stage where it is one of the most widely investigated areas of materials chemistry. The field has impacted many areas of science including commercial applications from gas storage agents to new investigations as drug-delivery vehicles [1]. Coordination polymers and MOF...
متن کاملMellitate Coordination Polymers
Accepted Manuscripts are published online shortly after acceptance, which is prior to technical editing, formatting and proof reading. This free service from RSC Publishing allows authors to make their results available to the community, in citable form, before publication of the edited article. This Accepted Manuscript will be replaced by the edited and formatted Advance Article as soon as thi...
متن کاملSupramolecular Chirality in Dynamic Coordination Chemistry
Labile metal complexes have a useful coordination bond; which is weaker than a covalent C–C bond and is reversibly and dynamically formed and dissociated. Such labile metal complexes also can be used to construct chiral shapes and offer dynamic conversion of chiral molecular shapes in response to external stimuli. This review provides recent examples of chirality induction and describes the dyn...
متن کاملTuning the self-assembly and luminescence properties of lanthanide coordination polymers by ligand design.
Two new structure-related tripodal ligands featuring salicylamide pendant arms, 1,3,5-tris{[(2'-furfurylaminoformyl)phenoxyl]methyl}-2,4,6-trimethylbenzene (L(I)) and 1,1,1-tris{[(2'-furfurylaminoformyl)phenoxyl]methyl}ethane (L(II)) have been designed and synthesized with the ultimate aim of self-assembling lanthanide polymers with interesting luminescent properties. Among two series of Ln(III...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2008
ISSN: 0108-7673
DOI: 10.1107/s0108767308083001